I think Edge would win this match pretty easily. I have never been a huge fan of Steve Corino, but Edge has a lot to offer, he is a great superstar. He also has the hometown advantage, and I've said before I think that is often a great advantage to have. Generally you will get the crowd behind you no matter what gimmick you are using if you are in your hometown. I think the only thing Corino has over Edge, is probably the type of match. Edge was great when it came to things like TLC matches in the WWE, but Corino has the advantage of ECW matches here.
However I still think it will be pretty one sided, with Edge winning after 10 minutes.