Kurt Angle vs. Steve Austin - Unforgiven 2001
Back in the summer of 2001 Kurt Angle and Steve Austin were feuding over the WWF Championship. The feud had begun as merely who could get the most affection from Vince McMahon, but because of Austin's betrayal of the WWF, the feud started to become more personal, culminating in both men wanting to rip each other apart before SummerSlam. The two engaged in a war of a match at SummerSlam, which saw Angle moments away from winning before Nick Patrick disqualified Austin for repeatedly hitting referees. Angle was pissed and rightfully so.
This lead to Angle pouring Austin with milk, mirroring Austin's own antics from before WrestleMania 15. Austin then stole Angle's medals, throwing them into a river. Angle stepped things up, kidnapping Austin and threatening to do the same thing to Austin that he had done to Angle's medals. That was unless Angle got his rematch at Unforgiven in Angle's hometown of Pittsburgh. Sure enough, Austin accepted the challenge.
Angle proceeded to beat Austin in a tag match before Austin attempted to re-injure Angle's neck that he broke during the Olympics 5 years earlier. Austin delivered a piledriver to Angle, re-injuring his neck. Angle wasn't 100% cleared to wrestle, but he returned before the night was out, declaring that he would become the champion in a passionate promo.
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The match itself wasn't as good as the SummerSlam encounter, but the moment after Angle won was great. His family and friends invaded the ring as did various WWF wrestlers in a great moment. Angle winning was a great moment, especially when you pair it with the events of 9/11 just recently occurring and Angle of course being the all American hero. Wonderful moment.