I like both teams and how can you not. If you were the type of fan to cheer the Heels and boo the Faces, you would enjoy both teams work as well.
On one side, you had the 11 time WWE World Champion, Edge teaming with the 9 time WWE World Champion, Randy Orton. Think Two-Man Power Trip 2006 version. They were the only two Superstars at the time that could go toe to toe with DX. Who knows how far they would have gotten if Triple H didnt get injured during their feud. I would have loved for them to expand their tag team to a Stable, but greed led to the end of the Age of the Rated RKO Era.
On the other side, you had the first Undisputed WWE World Heavyweight Champion, Chris Jericho teaming with the only man in history to hold the WWE, WCW, and ECW Championships (I still cant think of a name for this accomplishment, and Triple Crown just doesnt seem right
Triple World Crown maybe), The Big Show. Thanks to an unfortunate accident Edge suffered, Jeri-Show went on to become the Tag Team of Year in 2009. They faced the Colons, Legacy, Cryme Tyme, The Worlds Strongest Tag Team, Batista and Mysterio (Filthy Animals 2009), split up at Bragging Rights facing each other representing their respective shows, facing each other and Undertaker for the World Title, and finally facing DX.
Im going to go with Jeri-Show here, like there was ever any doubt. Rated RKO was great, but I think Jeri-Show was better. Now if Rated RKO faced London and Kendrick to unify the WWE and World Tag Team Titles
it might have been a closer race.