Ezekiel Jackson & Mason Ryan - Two powerhouses who aren't doing anything at the moment.
The Miz & Alex Riley - The two former friends should reunite as faces.
Curt Hawkins & Zack Ryder - Hawkins should turn face and reunited with Ryder. If neither of them are going to get a serious singles push, then they should be put in the tag division.
Alberto Del Rio & Ricardo Rodriguez - Ricardo needs to be wrestling already. He can do his own introduction before segueing into the normal Del Rio introduction.
The Kings of Wrestling - They don't have to necessarily be thrust into the tag division right away. Just maybe have Kassius debut by interfering in Cesaro's matches and helping him retain the U.S. Title.
Johnny Curtis & Derrick Bateman - These two guys are too funny and too entertaining to not have them on TV right now.
I would also pair John Cena & Randy Orton together as a mega star team. Just keep them from being too over powered and don't have them run everyone over. Just use their star power to give the tag division a rub.